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ORIGINAL ARTICLE
Year : 2015  |  Volume : 4  |  Issue : 1  |  Page : 34

Degradation of di-2-ethylhexyl phthalate in aqueous solution by advanced oxidation process


1 Department of Environmental Health Engineering, Student Research Center, School of Health, Isfahan University of Medical Sciences, Isfahan, Iran
2 Environment Research Center, Research Institute for Primordial Prevention of Non-communicable Disease, Isfahan University of Medical Sciences, Isfahan, Iran

Correspondence Address:
Prof. Bijan Bina
Department of Environment Health Engineering, School of Health, Isfahan University of Medical Sciences, Hezar Jerib Ave., Isfahan
Iran
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Source of Support: Isfahan University of Medical Sciences, Conflict of Interest: None


DOI: 10.4103/2277-9183.170701

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Aims: This study was conducted to compare the effectiveness of conventional technologies, UV irradiation and ozonation process, and UV/O3 as advanced oxidation processes to remove phthalate from aqueous solutions. Materials and Methods: The initial concentration of di-2-ethylhexyl phthalate (DEHP) was 5 mg/L. The photolysis, ozonation, and UV/O3 processes were conducted separately at different contact times (5-30 min). Then, the DEHP residuals in the solutions were analyzed by gas chromatography mass spectrometry. The effect of ozone dosage was also evaluated in the range of 50-400 mg/h on DEHP degradation. Kinetic and the rate constants were determined. Results: The results indicated that using UV and ozonation alone, the maximum DEHP removal efficiency were 43% and 50%, respectively. The UV/O3 process considerably improved the degradation of DEHP up to 80%. The synergistic effect observed in the combined processes mainly due to the effects of UV in enhancing the ozone decomposition, led to higher degradation for 30 min treatment. A kinetic study showed the degradation in UV/O3 followed the first-order model. In addition, the maximum DEHP removal rate was 74% with 200 mg/h ozone dosage by ozonation alone process, but it was 93% at same condition by UV/O3 process. Conclusion: It could be found that the UV/O3 process is a method for DEHP degradation in aqueous solution and may be recommended as a supplement with other processes for treatment of solutions containing low DEHP concentrations.


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