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ORIGINAL ARTICLES
Heavy metal content in edible salts in Isfahan and estimation of their daily intake via salt consumption
Hajar Pourgheysari, Malihe Moazeni, Afshin Ebrahimi
2012, 1:8 (28 March 2012)
Aims:
In this study, the heavy metal contamination of consumable table salt, both unrefined and refined, was investigated. The provisional tolerable weekly intake (PTWI) of heavy metals just by edible salt, of the Isfahan population, was also estimated.
Materials and Methods:
Twenty samples of salt, including 15 refined and five unrefined were analyzed. Precision of the analysis was assured through repeated analysis of the five samples, which had a great demand in the city. The heavy metal content in the samples was analyzed with Flame Atomic Absorption Spectrometry (AAS) and Inductively Coupled Plasma (ICP). The PTWI of the metals was calculated by a formula and by using the Iranian average body weight.
Results:
The mean and standard deviations of cadmium (Cd), lead (Pb), arsenic (As), mercury (Hg), copper (Cu), and zinc (Zn), in refined table salts were 0.15 ± 0.02, 0.57 ± 0.1, 0.69 ± 0.09, 0.061 ± 0.008, 0.87 ± 0.11, and 6.34 ± 1.08 μg/g, and those in the unrefined ones were 0.16 ± 0.02, 0.61 ± 0.13, 0.63 ± 0.07, 0.058 ± 0.004, 0.86 ± 0.06, and 7.53 ± 2.93 μg/g, respectively. A PTWI via salt consumption was in the range of 0.8 - 3.1 percent.
Conclusions:
There was a significant difference between the heavy metal concentrations and their guideline values. Estimation of the health risk due to heavy metals was not possible as PTWI showed total intake of a metal by total food consumption during a week. Therefore, it was important to assess the public health risks arising from the presence of these toxic contaminants in the foods consumed by the population of Iran.
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An investigation on the lead and cadmium content in vegetables and irrigating water in some farms in Gorgan, Iran
Ali Shahryari, Yousef Dadban Shehamat
2012, 1:12 (28 March 2012)
Aims:
The objective of this study is to investigate the levels of lead (Pb) and cadmium (Cd) in the vegetables from the farms of Gorgan, Iran, and compare them with the permissible levels proposed by the Food and Agriculture Organization (FAO) and World Health Organization (WHO) standard.
Materials and Methods:
In this descriptive study, 40 samples of irrigating water and vegetables were collected, between the periods of August and December 2008. The Polarography apparatus was used to determine the amount of cadmium and lead after sample preparation. The level of significance was set at 5% for all the tests
Result:
The cadmium concentrations in spinach, garden cress, and radish were 0, 0.085, and 1.56 μg.kg
-1
, respectively. The lead concentrations in spinach, garden cress, and Radish were 51.21, 40.13, and 87.27 μg.kg
-1
, respectively. The cadmium concentration in irrigating water was not detectable with the Polarography apparatus. However, the lead concentration in water was 26.75 μg.kg
-1.
There was no significant variation between the cadmium levels in spinach and garden cress (
P
<0.05), while there was a significant difference between the amount of cadmium in radish and spinach and garden cress (
P
<0.05).
Conclusion:
All the vegetables and water contained Pb, although Cd was lower than the permissible levels proposed by FAO/WHO and might not cause health hazards to consumers.
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1,579
174
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Catalytic oxidation of hydrogen peroxide and the adsorption combinatory process in leachate waste pretreatment from composting factory
Behrooze Karimi, Mohammad Hassan Ehrampoush, Asghar Ebrahimi, Mehdi Mokhtari, Mohammad Mehdi Amin
2012, 1:15 (28 March 2012)
Aims:
The purpose of this study was to use a combinational process of catalytic oxidation of hydrogen peroxide (CWPO) and activated carbon for improving the removal efficiency of organic matter.
Materials and Methods:
The effect of the operational parameters such as residence time (30 - 90 minutes), reaction temperature (100-300°C) in the pressure 10 bar, and catalytic iron concentration were investigated. The effect of the catalytic method, catalytic wet peroxide oxidation (CWPO), along with the absorption process, on granular activated carbon (GAC), powdered activated carbon (PAC), PAC/Cl
2
, and GAC/Fe were considered; oxygen is used to supply pressure and H
2
O
2
is applied as the main oxidant in various concentrations.
Results:
The removal efficiency of the chemical oxygen demand (COD) was over 35%, obtained in one hour of retention time, with the wet air oxidation (WAO) process, and the removal efficiencies of GAC, PAC, and PAC/Cl
2
, at a temperature of 300°C, and activated carbon concentration of 2 g/l, were 43.4, 38.9, and 33.6%, respectively.
Conclusion:
These results indicate that the reaction temperature, residence time, and H
2
O
2
dose are the most important factors affecting the degradation of organic matter. The GAC/Fe catalyst process had a higher efficiency than other absorbents for organic matter oxidation.
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Detection of
E. coli
O157: H7 by immunological and real-time PCR methods in the water treatment plant
Peymaneh Atabakhsh, Mohammad Mehdi Amin, Hossein Mortazavi, Parinaz Poursafa, Majid Yaran, Abbas Akhavan Sepahi, Mohammad Jalali, Ashraf Al sadat Noohi
2012, 1:6 (28 March 2012)
Aims:
There is limited data on the occurrence of
E
.
Coli
O157: H7 in water. Therefore, this study aims to detect
E
.
Coli
O157: H7 in the Water Treatment Plant (WTP).
Materials and Methods:
This cross-sectional study was conducted in Isfahan WTP, central of Iran. Immunological methods were implemented with anti-serum kits and the molecular method of reverse transcription-polymerase chain reaction (RT-PCR) was used to detect
E
.
Coli
O157: H7 in eight locations of the WTP; the sludge of the sedimentation basin and filter backwash water were also monitored. The survival of
E
.
Coli
O157: H7 in the sludge samples of the sedimentation basin was indicated by the formation of agglutination particles using the immunological method, and through indicator probes using the RT-PCR method.
Results:
E. Coli O157: H7 was not detected in the water samples from the WTP units. The removal percent of total coliforms (TC), fecal coliforms (FC), and Heterotrophic Plate Count (HPC), respectively, were as follows: 59.5, 49, and 54.8% in the sedimentation basin; 66, 45.8, and 57% in the ozonation system; 98.8, 98, and 78.8% in the filtration system; and 96, 100, 91% in the disinfection system. Conclusions:
This study revealed the existence of the pathogenic coliform of
E
.
Coli
O157: H7 in the sludge of the sedimentation basin. The absence of
E
.
Coli
O157: H7 in the finished water indicated that the WTP units were able to eliminate these pathogenic bacteria before reaching the final units of the plant, including the filtration and disinfection systems.
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Determination of design parameters of urban wastewater treatment plants in the cold regions of Iran
Mehraban Sadeghi, Hassan Hashemi, Fahimeh Teimouri
2012, 1:13 (28 March 2012)
Aims:
This study has been conducted to focus on the localization of the design parameters used for the design of wastewater treatment plants in a region of Iran.
Materials and Methods:
Three wastewater treatment plants were selected (as models) in a cold weather region of Iran. The main characteristics of the wastewater, such as, flow rate and its fluctuations, total solids, and the organic and nutrient contents, which play an important role in the design and operation of the wastewater treatment facilities, were measured for the selected plants during a year.
Results:
The averages of the design parameters for the investigated plants, including, biochemical oxygen demand (BOD
5
), chemical oxygen demand (COD), total suspended solids (TSS), volatile suspended solids (VSS), total Kjeldahl nitrogen (TKN), and total phosphorous (TP) were, 41, 60, 65, 47, 8.3, and 0.93 g/capita, respectively. Wastewater production was 177 lit/cap-day with a maximum and minimum coefficient of 1.76 and 0.29, respectively.
Conclusions:
Using design parameters based on the local characteristics and the real-world conditions of the wastewater, can result in more+operational efficiency in the wastewater plants. It is suggested that the results of this study can be applied to the design of wastewater facilities throughout Iran, with the same local conditions.
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The effect of the waste separation policy in municipal solid waste management using the system dynamic approach
Ahmad Jamshidi Zanjani, Mohsen Saeedi, Behdad kiani, Ali Vosoogh
2012, 1:5 (28 March 2012)
Aims:
In the present study, Vensim was used to simulate waste management system of Tehran, the capital of Iran, with the system dynamic approach.
Materials and Methods:
The environmental system dynamic modeling is one of the comprehensive simulation tools capable of simulating and analyzing complex systems. In this approach, the model is developed based on the existing realities and userâ€'comments. User participation to develop the model could increase the reliability of the results.
Results:
The simulation results revealed good conformity with the statistical data. Waste production prediction in the model with real data was more than 95%. Moreover, the effect of applying an encouraging policy for people to separate their waste was considered. The result indicated that applying a new policy, and the economic benefit through this policy would prevent getting a loan from the government after 20 years.
Conclusions:
It could be concluded that public participation in waste separation was an effective policy to help in the financial independence of the municipality in terms of urban waste management. Moreover, conformity between the simulation results and real data revealed an appropriate capability of the simulated model to predict Tehran waste generation.
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Influence of electrical conductivity on the phytoremediation of contaminated soils to Cd
2+
and Zn
2+
Maryam Salimi, Mohammad Mehdi Amin, Afshin Ebrahimi, Akbar Ghazifard, Payam Najafi
2012, 1:11 (28 March 2012)
Aims:
This research was conducted to study the effects of the electrical conductivity (EC) of irrigation water and compost on the Cadmium (Cd) and Zinc (Zn) uptake by sunflower,
Helianthus annuus
. The transfer of Cd and Zn from soils close to the Zn mine, to the sunflower tissues, and the interactions between the two concerned metals, were also investigated.
Materials and Methods:
For this purpose, 10% weight/weight from municipal composts was applied to raw soils that were randomly collected from the mine region. Series analyses were also implemented by irrigation water, with EC values in the range of 0, 2, 4, and 6 dS/m.
Results:
The maximum uptake rate of Cd, with EC levels of 6 dS/m, in plant samples was 4.82 μg/g for the roots, 6.14 μg/g for the stems, and 5.4 μg/g for the leaves; and the maximum uptake of Zn, in plants irrigated with tap water, was 241 μg/g by the roots, 624 μg/g by the stems, and 229 μg/g by the leaves, respectively.
Conclusions:
Results showed that high EC levels of irrigation water increased Cd accumulation and decreased Zn accumulation in the shoots. The presence of high EC levels in irrigation water negatively affected biomass production by plants. Chlorine ion (Cl-) had a positive influence on Cd accumulation in the harvestable parts of the plant.
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Effectiveness of nanozeolite modified by cationic surfactant in the removal of disinfection by-product precursors from water solution
Amir Mohammadi, Bijan Bina, Afshin Ebrahimi, Yaghoub Hajizadeh, Mohammad Mehdi Amin, Hamidreza Pourzamani
2012, 1:3 (28 March 2012)
Aim:
In this study the performance of a natural nanozeolite, modified with a cationic surfactant, on the adsorption of humic acid from water was investigated in a batch system.
Materials and Methods:
Clinoptilolite as a natural nanozeolite was modified with different doses of a cationic surfactant solution, hexadecyltrimethylammonium bromide (HDTMA-Br), at dosages from 0.5 to 10 g/l. The modified adsorbents were individually added to synthetic water samples containing a known amount of humic acid and put on the shaker for two hours, at room temperature. Humic acid (HA) concentrations, turbidity, and pH were measured before and after the adsorption process.
Results:
According to the results obtained, and based on the statistical analysis (Pearson correlation statistical test), there was a clear correlation between the cationic surfactant dosage and HA removal (
P
value
<0.001, r=0.87). By increasing the HDTMA-Br dosage, the ratios of turbidity/turbidity
initial
and UV
254
/UV
254-initial
adsorbance by HA (after/before adsorption process) were decreased. In HDTMA-Br dosages of 7 and 10 g/l, the maximum removal efficiency for HA was 96 and 86%, respectively, with a slight variation in the pH value and turbidity unit.
Conclusions:
This study showed that modification of nanozeolite by cationic surfactants, to reduce its negative surface charge, could markedly improve its efficiency in the adsorption of disinfection by-product precursors from an aqueous solution. The HDTMA-Br/Clinoptilolite nanozeolite (CNZ) ratio of 0.07, pH have to coincide in iso-electric point, can be an optimum ratio for the modification.
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Noise pollution of air compressor and its noise reduction procedures by using an enclosure
Farhad Forouharmajd, Parvin Nassiri, Mohammad Reza Monazzam
2012, 1:20 (15 May 2012)
DOI
:10.4103/2277-9183.96143
Aims:
The aim of this study is to find manners of noise abatement to reach to its allowable values by which the noise caused by compressors can be reduced, and if use of enclosure is an effective alternative.
Materials and Methods:
In the study, analysis of noise caused by the compressor and how distribution of sound frequencies with and without the use of enclosure was done, and then compared with standard values to help choose the best absorber material. This method is in accordance with the
in situ
assessment techniques for noise generated by different sources. A second order analyzer was use to study the recorded sound pressure level (SPL) values, and to demonstrate which frequencies can be more important in designing the enclosure. A sheet metal was used for enclosing the compressor, and this was lined with an absorber material to achieve a better sound reduction. SPL levels, before and after the enclosure of the compressor with the sheet material, were measured and compared.
Results:
There was a reduction in the level of noise produced for all frequencies due to use of the enclosure, a difference of 10 to 50 dB of reduction was recorded for all the frequencies. For higher frequencies in the range of 500 Hz to 4000 H, the SPL showed a similar reduction. A reduction of 50 dB in the produced noise below the standard was seen for the frequency of 63.5 Hz in octave band frequencies. There was also a permissible limit for higher frequencies of noise produced by the compressor, but with a gap of 10 dB of its standard limit at the frequency of 500 Hz.
Conclusions:
An overall noise reduction by 25 dB with the use of mineral wool as an extra liner on the inside of the enclosure, suggests that the effectiveness of the enclosure can be increased by using such absorber materials.
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Performance evaluation of an Anaerobic Migrating Blanket Reactor in the biodegradation of perchloroethylene from industrial wastewaters
Mohammad Mehdi Amin, Maryam Faraji, Fariborz Momenbeik, Akbar Hasanzadeh, Mohsen Sadani
2012, 1:1 (28 March 2012)
Aims:
The aim of this study is to determine the PCE biodegradation potential in an Anaerobic Migrating Blanket Reactor (AMBR) that has not been used so far for the bioremediation of this compound, in high concentration, and to evaluate the system performance.
Materials and Methods:
This study was an Experimental - Interventional study that was done from April 2010 to March 2011, in the Isfahan University of Medical Sciences. The AMBR was used in a type of laboratory scale, with a volume of 10 L, which was divided into four compartments, for the biological degradation of PCE in a synthetic substrate. The startup was done using anaerobic digested sewage sludge. The performance of the reactor was evaluated during four periods, with a PCE loading rate of 3.75 until 75 mg PCE/L.d. The hydraulic retention time (HRT) was 32 hours.
Results:
Optimum chemical oxygen demand (COD) removal efficiency was obtained, 98%, with an organic loading rate (OLR) equal to 3.1 g COD/L.d. For PCE removal, the optimum efficiency was observed to be 99.8%, with a PCE loading rate equal to 37.5 mg PCE/L.d. The average COD and PCE removal rates for the whole activity period of the reactor were 91.4 and 99.5%, respectively; 1.1 ± 0.7% from the influent PCE was adsorbed on the biomass and 20% was found in the headspace.
Conclusions:
The AMBR reactor, which provides full-scale studies and uses real industrial wastewater polluted with PCE, is a simple, efficient, and reliable method for the treatment of PCE.
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934
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The evaluation of heat stress through monitoring environmental factors and physiological responses in melting and casting industries workers
Habibollah Dehghan, Seyed Bagher Mortazavi, Mohammad Javad Jafari, Mohammad Reza Maracy, Mahdi Jahangiri
2012, 1:21 (15 May 2012)
DOI
:10.4103/2277-9183.96144
Aims:
Evaluation of heat stress in workers exposed to hot/dry conditions of melting and casting industry is imperative for management of heat stress. This study aims to compare results of heat strain evaluation by monitoring environmental factors and physiological responses.
Materials and Methods:
This is a cross-sectional study that was conducted on 51 workers of a large melting and casting company in 2010. Wet Bulb Globe Temperature (WBGT) index, heart rate and ear canal temperature were measured by WBGT meter, heart rate monitor and personal heat stress monitor, respectively. Physical activity intensity was assessed based on the ratings of perceived exertion (RPE). Data were analyzed using descriptive statistics and Pearson correlation test.
Results:
WBGT index in 64.7% of workstations exceeded 30°C and in 41.2% was over 32°C. The value of WBGT index in 69% of work stations exceeded the threshold limit of the ACGIH standard. The physiological strain index (PSI) in 31% of worker was higher than 5, although its mean measured at 3.8 (1.8). Increase in the ear canal temperature in 64.7% of cases (33 persons) was over 1°C. Correlation between WBGT index with ear canal temperature and PSI index, adjusted body mass index and age, was 0.67 and 0.69 (
P
< 0.0001).
Conclusion:
In hot/dry conditions of melting and casting processes, despite moderate correlation between WBGT index with ear canal temperature and PSI index, work-rest cycles of WBGT index is not applicable for many of the workstations. Therefore, heat stress evaluation based on physiological variables probably has higher validity and is more appropriate.
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866
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Active noise cancellation of low frequency noise propagating in a duct
Farhad Forouharmajd, Parvin Nassiri, Masoumeh Ahmadvand, Farshad Forouharmajd
2012, 1:24 (15 May 2012)
DOI
:10.4103/2277-9183.96005
Aims:
The object is to find a manner of reduction primary noise from a source by an electro acoustic device that cancels unwanted sound by generating an anti sound (anti noise) of equal amplitude and an opposite phase is described as an active noise control system.
Materials and Methods:
In this method, the primary noise is acquired via a microphone, and the anti noise propagates with the same amplitude and the reverse phase at the primary noise path via a speaker to cancel the original noise. The effectiveness of cancellation of the primary noise depends on the accuracy of the amplitude and phase of the generated anti noise.
Results:
The results present a noise reduction of 16 dB until 20 dB overall. A change in the system setup and noise power can reach a noise reduction up to 25 dB. Perhaps, this is due to the background noise and primary noise differences that create a powerful anti noise for canceling the original noise.
Conclusions:
With regard to the wide range of frequencies of different noise sources, having optimized circumstances in the duct, microphone location on the duct body or even the distance of the speakers may be important in signal processing, noise sampling and anti noise production.
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837
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Ability of phytoremediation for absorption of strontium and cesium from soils using
Cannabis sativa
Parisa Seyed Hoseini, Parinaz Poursafa, Faramarz Moattar, Mohammad Mehdi Amin, Amir Hossein Rezaei
2012, 1:17 (15 May 2012)
DOI
:10.4103/2277-9183.96004
Aims:
This study is aimed at assessing the effectiveness of
Cannabis sativa
in the absorption of cesium and strontium elements from the soil.
Materials and Methods:
This study was conducted in 2011, in Tehran, Iran. We employed the phytoremediation technology to refine the contamination of soil with radioactive material such as cesium and strontium.
Cannabis sativa
was selected because of its capability for potential radioactive absorption. It was planted in various soils with different concentrations of cesium and strontium (20 ppm, 40 ppm, 60 ppm, and 80 ppm), and after sufficient growth for about six months, it was separated into root, stem, and leaves for measuring the absorption of these elements in the main parts of the plant. The samples were measured by using the Inductively Coupled Plasma (ICP) method.
Results:
Strontium absorption and the main parts of the plant showed a significant relationship. The percentage of strontium absorption was 45% in the root, 40% in the stem, and the minimum absorption was found in the leaves (15%), but the corresponding figure was not significant for the cesium element. A strontium concentration of 60 ppm was possibly the maximum absorption concentration by
Cannabis
.
Conclusion:
Our findings suggest that strontium can be absorbed by
Cannabis sativa
, with the highest absorption by the roots, stems, and leaves. However, cesium does not reach the plant because of its single capacity and inactive complex formation.
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Treating municipal solid waste leachate in a pilot scale upflow anaerobic sludge blanket reactor under tropical temperature
Abbas Alizadeh Shooshtari, Mohammad Mehdi Amin, Ramin Nabizadeh, Nemat Jaafarzadeh
2012, 1:7 (28 March 2012)
Aims:
The objective of this study was to investigate an Upflow Anaerobic Sludge Blanket (UASB) reactor efficiency in treating municipal landfill leachate, under tropical temperature.
Materials and Methods:
A 30-liter pilot-scale UASB reactor was used to treat the municipal solid waste leachate, under tropical temperature, for 230 days. The reactor was inoculated with 10 liters of anaerobic sludge from an anaerobic digester, in an agro industry's wastewater treatment plant. The Volatile Suspended Solids (VSS) of sludge were 65 g/L, with volatile suspended solids to suspended solids (VSS/SS) ratio of 0.74. The reactor was operated in mesophilic (34 - 39°C) temperature.
Results:
After reaching a stable operation, the reactor was exposed to raw leachate, with mean chemical oxygen demand (COD) concentrations of 35 g/L. The leachate was diluted to 9 - 10 g/L at Organic Loading Rates (OLRs) of 2, 6, 12, 15 g COD/L.d and decreased again to 12 g COD/L.d, resulting in 45, 76, 84, 68, and 79% removal efficiency and increased again to 87% removal efficiency for COD, at Hydraulic Retention Times (HRTs) of 6, 1.6, 0.83, and 0.67 days, respectively, in the UASB. In the reactor used in this study, the heavy metals were removed by adsorption on biomass, and the maximum removal rate was 68% for Zinc (Zn).
Conclusions:
It was concluded that the optimum OLR for diluted leachate up to 10 g COD/l, was 12 g COD/L.d at an HRT of 0.67 day (16 hours).
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Feasibility energy recovery potential of municipal solid waste in Northwest of Iran
Amir Mohammadi, Afshin Ebrahimi, Mohammad Mehdi Amin
2012, 1:14 (28 March 2012)
Aims:
The goal of this study was the ultimate analysis and chemical composition of SW for energy recovery in Urmia city.
Materials and Methods:
A cross-sectional, descriptive study was done on municipal SW in Urmia city, northwest of Iran. The samples were collected during the four seasons of a year. Experiments were analyzed according to the American Society for testing and Materials (ASTM) Method D 5231-92. The chemical composition of the SW was calculated, to determine the quantity of produced biogas and heat value.
Results:
The findings showed that food waste percent had been 68.9%, carbon/nitrogen (C/N) 18.33, containing 10.4% ash and 54% moisture. The calculated chemical composition of organic SW was (C
27.7
H
43.1
O
15.3
N
1
S
0,065
) with a heat value of the 2.2 × 10
4
Kj/Kg. The produced methane and heat value of the biodegradable organic SW, chemical formula C
23.63
H
37.52
O
14.65
N
1
S
0.069
, were 212 liters (151 g) and 9992 Kj per 1 Kg of SW.
Conclusions:
The recovery of SW energy through incineration was a better choice, due to the high heat value. However, it would produce more than 300 tons/day of greenhouse and poison gases, but land filling produced 200 tons/day of different gases. Thus, on the basis of the calculated SW composition in this research, it seemed that energy recovery through methane collection was a better option for this study area.
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Biodegradation of benzene-toluene-xylene in petrochemical industries wastewater through anaerobic sequencing biofilm batch reactor in bench scale
Maryam Estebar, Mohammad Mehdi Amin, Parinaz Poursafa, Mohammad Ghasemian, Neamat Jaafarzadeh, Hassan Hashemi, Ali Fatehizadeh
2012, 1:22 (15 May 2012)
DOI
:10.4103/2277-9183.96145
Aims:
This study aims to evaluate the performance of the anaerobic sequencing batch biofilm reactor (ASBBR) for biodegradation of Benzene-Toluene-Xylene (BTX) that is present in petrochemical synthetic wastewater.
Materials and Methods:
A laboratory-scale ASBBR was used to treat a synthetic substrate mixture representing petrochemical wastewater that contained BTX. The operation schedule was: Fill time: 10 minutes, reaction time: 22.8 hours, settling time: 60 minutes, and decant time: 10 minutes, at 35C. The BTX samples were analyzed by gas chromatography-flame ionization detector (GC-FID) equipped with head space.
Results:
After reaching to stable operation, the reactor was exposed to influent BTX concentrations of 5, 20, and 50 mg/l, with overall organic loading rate of 3 g COD/l.d resulting in 61, 79, and 50% removal efficiencies for the BTX, respectively. At this time, the removal efficiencies for COD were 75, 90, and 70%.
Conclusions:
The optimum BTX removal of 79% was achieved in 3 g COD/l.d and HRT of 3.8 days, at influent BTX concentration of 20 mg/l. Thus, it could be concluded that ASBBR was a feasible, efficient, and consistent technology for treatment of petrochemical wastewaters containing BTX. The ASBBR might be an alternative to intermittent systems as well as batch systems due to its superior operational flexibility.
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189
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Isotherms and kinetics studies of biosorption nickel (II) and chromium (VI) from aqueous solution by dried activated sludge
Mohammad Malakootian, Seyed Kamal Ghadiri, Nader Yousefi, Ali Fatehizadeh
2012, 1:2 (28 March 2012)
Aims:
The aim of this study is the recovery of municipal refuse and using it as a biosorbent for Nickel (II) and Chromium (VI) (Ni
2+ an
d Cr
6+
)removal from aqueous solutions.
Materials and Methods:
Activated sludge was obtained from the wastewater treatment plant in a dairy industry. All experiments were performed in the batch system and effective parameters such as the pH, adsorbent dosage, and the initial concentration and contact time of Ni
2+
and Cr
6+
were investigated. The adsorption isotherms and kinetics were evaluated to describe the metal uptake and dynamic reactions.
Results:
The results of this study showed that with an increasing adsorbent dose and contact time, Ni
2+
and Cr
6+
removal efficiency increased. The maximum adsorption of Ni
2+
and Cr
6+
was obtained in pH 6 and 2, respectively. Meanwhile, with increasing Ni
2+
and Cr
6+
concentration, the removal efficiency decreased. The results best fitted the Langmuir isotherm and the maximum absorption capacity of Ni
2+
and Cr
6+
onto dry activated sludge (DAS) were 2.17 and 2.23 mg/g, respectively. Analysis of the adsorption kinetics showed that the intraparticle diffusion kinetic had been good and presented Ni
2+
and Cr
6+
uptake onto DAS, and the intraparticle diffusion rate constant of Ni
2+
and Cr
6+
were 0.044 and 0.042 (mg/g min
0.5
), respectively.
Conclusions:
According to the results, dry activated sludge is suggested as a low cost and available adsorbent for removing Ni
2+
and Cr
6+
from aqueous solutions.
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Antibacterial effects of hydrogen peroxide and silver composition on selected pathogenic enterobacteriaceae
Mojtaba Davoudi, Mohammad Hassan Ehrampoush, Tahereh Vakili, Abdorrahim Absalan, Asghar Ebrahimi
2012, 1:23 (15 May 2012)
DOI
:10.4103/2277-9183.96148
Aims:
Antibacterial effects of hydrogen peroxide and silver composition on selected pathogenic enterobacteriaceae was investigated in this study.
Materials and Methods:
The efficacy of 30 ppb silver in 0.3% hydrogen peroxide solution for inactivation of selected Enterobacteriaceae, including
Escherichia coli, Proteus mirabilis,
and
Klebsiella pneumoniae
was assessed for 72 hours in a designated nutrient broth medium and steel surface. The bactericidal growth ability was determined for each bacterium genus by the conventional colony count method and turbidimetry via an optical density (OD) assay at 450 nm in a time interval of 24 hours.
Results:
Suspensions of
K.pneumoniae
, and
P.mirabilis
showed a significant OD reduction at three 24-hour intervals (CI = 0.95;
P
< 0.05, for both), along with blocked growth in a designated broth medium during 24 to 48 hours of exposure. The disinfectant was also significantly efficient for inactivating of the mentioned bacteria on steel surfaces after a 15-minute time exposure (CI = 0.95;
P
< 0.05). For
E.coli
, the OD decreased slightly during the initial exposure time, but increased after 24 hours. Viable
E.coli
cells were proved by colonies grown on the plate. A qualitative surface decontamination test showed that three pathogenic bacteria were inactivated significantly after disinfectant exposure (CI = 0.95,
P
< 0.05).
Conclusions:
In conclusion, a combination of hydrogen peroxide and silver ions was proposed as a strong disinfecting agent both in suspensions and on the surfaces against these three important human pathogens.
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Determination of malachite green in trout tissue and effluent water from fish farms
Abbas Khodabakhshi, Mohammad Mehdi Amin
2012, 1:10 (28 March 2012)
Aims:
The objective of this study was to determine the malachite green (MG) concentration in trout tissue and the effluent water of fish farms, at one of the largest trout fishery industries in Iran.
Materiels and Methods:
Twelve samples of water and fish tissue were collected from fish farms placed at the upstream ends of two large rivers in the study area. The samples, after extraction, were analyzed with liquid chromatography-mass spectrometry (LC-MS). The effluent water samples were also analyzed by the spectrophotometric method after cloud point extraction using the anionic surfactant Triton X-100.
Results:
The concentration of malachite green in the fish samples ranged from 265.2 to 1663 μg/kg, which is more than the recommended maximum allowable concentration by the Codex standards. MG in the water samples ranged from 5.65 ng/L to 384 μg/L. The equivalent concentrations of MG in the two large rivers in the study area were 1.78 and 0.62 ng/L, and the total MG load for these two rivers, with a fish production rate of 10,000 tons per year, was around 644 kg/d.
Conclusion:
We concluded that the concentration of MG used as an antimicrobial chemical in trout fish tissues and water samples in this study were out of compliance with the existing standards. Therefore, the fish products of these farms could cause serious public health hazards, and the discharge of the effluent from these farms, without treatment, posed potential environmental problems.
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An ergonomic study in building demolition: Assessment of musculoskeletal disorders risk factors by PATH method
Mohammad Hajaghazadeh, Yosef Mohammadian, Mohammad Normohammadi, Mehdi Zare
2012, 1:43 (13 October 2012)
DOI
:10.4103/2277-9183.102386
Aims:
The aim of this study was the investigation of musculoskeletal disorders risk factors among building demolition workers.
Materials and Methods:
Posture, activity, tools, and handling (PATH) method as a work sampling method was applied to record the postures, activities, and handling of building demolition workers in four tasks. The percentage of working time is reported for each item to compare the risk factors in tasks. Nordic musculoskeletal questionnaire also was used to study the prevalence of musculoskeletal disorders over 12 months.
Results:
Trunk, leg(s), and arm(s) postures differed significantly among tasks. Neutral arm posture and non-neutral leg(s) and trunk postures were observed frequently. Manual materials handling (MMH) activities are distributed differently among tasks. Moving was the most observed (35%) and carrying was the less observed (11.8%) MMH activity. Gross grasp was the most observed (78.5%) hand activity in building demolition workers. The most observed weight category was 0 kg≤load<5 kg. Low back had the highest prevalence of MSDs symptoms (91.1%) and hip had the lowest prevalence of symptoms (6.7%).
Conclusions:
PATH is applicable to building demolition process. Ergonomic intervention is necessary in high prevalence body regions such as lower back and wrist to decrease the symptoms. With respect to the results of PATH method, ergonomic interventions for trunk and leg(s) are necessary in all tasks, but only task #3 is in the priority of arm(s) intervention.
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Outdoor investigation of air quality around Bandar Abbas - Iran oil refinery
Mehdi Zare, Ali Toolabi, Mohammad Reza Zare, Maryam Sarkhosh, Amir Hossein Mahvi, Ayat Rahmani, Ali Fatehizadeh
2012, 1:9 (28 March 2012)
Aims:
This study has been conducted to assess air pollution, with respect to particulate matter less than 10 μm in diameter (PM
10
), sulfur dioxide (SO
2
), carbon monoxide (CO), nitrogen dioxide (NO
2
), hydrogen sulfide (H
2
S), and the Air Quality Index (AQI), in a location at close proximity to the Bandar Abbas-Iran oil refinery.
Materials and Methods:
In this study, a location with close proximity to Bandar Abbas oil refinery was selected as the sampling station. The Air Sampling period was from June to September 2010. In order to assess PM
10
concentrations, the samples were collected using a high volume sampler with fiberglass filters. To measure the concentrations of other air pollutants, including, SO
2
, CO, H
2
S, and NO
2
, real-time instruments were used. With regard to air pollutant concentrations, the AQI values were calculated and for the wind rose, the effect of the oil refinery on Bandar Abbas was evaluated.
Results:
According to the results from the present study, PM
10
, SO
2
, nd NO
2
concentrations were higher than the recommended values of the national ambient air standards. The maximum PM
10
and SO
2
concentrations and their resultant AQI values were observed in August and September, respectively. Other air pollutants had their highest concentrations in July and September, but in no case did they exceed the standard values.
Conclusion:
The three most significant outdoor problems with the air quality around Bandar Abbas oil refinery were the NO
2
, SO
2
, and PM
10
levels.
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Combination of wet bulb globe temperature and heart rate in hot climatic conditions: The practical guidance for a better estimation of the heat strain
Habibollah Dehghan, Seyed Bagher Mortazavi, Mohammad Javad Jafari, Mohammad Reza Maracy
2012, 1:18 (15 May 2012)
DOI
:10.4103/2277-9183.96006
Aims:
The aim of this study is to evaluate the combined application of wet bulb globe temperature (WBGT) and physiological strain Iindices based on heart rate (PSI
HR
) for the estimation of heat strain, in hot climatic conditions.
Materials and Methods:
This cross
-
sectional study was conducted on 122 men including 71 and 51 workers from the Assaluyeh National Petrochemical Company and Isfahan Steel Company in the center and south of Iran, respectively. The WBGT index, heart rate, and auditory canal temperature were measured at rest and when working. The data were analyzed using descriptive statistics and logistic regression.
Results:
The results of the logistic regression indicated that the WBGT index was a poor predictor of heat strain and its sensitivity and specificity were 53 and 65%, respectively. However, the combined application of the WBGT and PSI
HR
indices was a better predictor of heat strain, and the sensitivity and specificity of this combination were 75 and 69%, respectively.
Conclusion:
According to the results of this study, the combined application of the WBGT and PSI
HR
indices can be used as a valid estimator of heat strain in hot climatic conditions in the center and south of Iran.
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172
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Performance of raw and regenerated multi- and single-walled carbon nanotubes in xylene removal from aqueous solutions
Hamidreza Pourzamani, Bijan Bina, Alimorad Rashidi, Mohammad Mehdi Amin
2012, 1:4 (28 March 2012)
Aims:
The ability of raw and recycled multi- and single-walled carbon nanotubes (MWCNT and SWCNT) for xylene adsorption from aqueous solutions was evaluated.
Materials and Methods:
Batch adsorption experiments were conducted in 110 ml glass bottles. Gas chromatography-mass spectrometry was used for xylene measurement and the carbon nanotube characteristics were evaluated with the help of a transmission electron microscope.
Results:
With a carbon nanotube dose of 1 g/l, xylene concentration of 10 mg/l, pH 7, and a contact time of 10 minutes, the equilibrium adsorption capacity (q
e
(mg/g)) of SWCNT was 9.2 mg/g, which was higher than that for MWCNT (8.9 mg/g). The SWCNT revealed a better performance for xylene sorption than the MWCNT. Results of a desorption study showed that xylene adsorbed onto the SWCNT and MWCNT can be easily desorbed at 105 ± 2°C.
Conclusions:
It is concluded that recycled carbon nanotubes on heating for the first time, show a better performance for xylene adsorption than when they are raw. The SWCNT are efficient as xylene adsorbents in an environmental pollution cleanup.
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Isotherms and kinetics of lead and cadmium uptake from the waste leachate by natural and modified clinoptilolite
Maryam Faraji, Ehsan Abooi Mehrizi, Mohsen Sadani, Mostafa Karimaei, Esmaeil Ghahramani, Kamal Ghadiri, Mohammad Sadegh Taghizadeh
2012, 1:26 (12 July 2012)
DOI
:10.4103/2277-9183.98385
Aims:
The purpose of this study is to investigate the feasibility of the absorption of lead and cadmium from the leachate, by natural zeolite clinoptilolite and improving the zeolite ability by a modified surface.
Materials and Methods:
To examine the absorption ability of these two metals (lead and cadmium), the variables, such as, type of sorbent, sorbent concentration, and contact time were studied. Zeolite samples were analyzed by X-ray florescence, the spectrum of X-ray diffraction, and Brunauer-Emmett-Teller (BET).
Results:
The absorption efficiency of the modified zeolites were increased from 4.2 and 5.3 percent to 71.6 and 75.2 percent for lead and cadmium, respectively. With increasing the surfactant concentration from 2 to 20 mmol/L, the absorption efficiency of modified zeolite for lead and cadmium was increased to 71 and 74%, respectively. The best isotherm model for lead adsorption was Freundlich model, with a determination coefficient equal to 0.99, and for cadmium it was Langmuir model with a determination coefficient equal to 0.99.
Conclusions:
The modified zeolite with surfactant can be used as an appropriate adsorbent for the separation of heavy metals from waste Leachate. Lead and cadmium were absorbed in a single layer on the surface of the modified zeolite with surfactant, comparing different isoterm models, indicated that the capacity of the modified zeolite for lead adsorption was more than cadmium adsorption, but cadmium was absorbed with higher energy.
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Evaluation of flat sheet membrane bioreactor efficiency for municipal wastewater treatment
Somayeh Fazeli, Ali Fatehizadeh, Amir Hesam Hassani, Ali Torabian, Mohammad Mehdi Amin
2012, 1:19 (15 May 2012)
DOI
:10.4103/2277-9183.96008
Aim:
In this paper, the feasibility of flat-sheet membrane bioreactor (FS-MBR) for municipal wastewater treatment was studied.
Materials and Methods:
In this study, treatment of municipal wastewater in a submerged FS-MBR was investigated under different aeration time and flux. A bioreactor consist of microfiltration membrane (MF) and actual municipal wastewater as influent stream. The FS-MBR was operated during 161 days.
Results:
The result showed that average removal efficiencies of chemical oxygen demand (COD), biological oxygen demand (BOD
5
), total suspended solids (TSS) and volatile suspended solids (VSS) were obtained >90% and with variation of influent COD, BOD
5
, TSS and VSS, the removal efficiency no significantly change. The mixed liquor-suspended solids (MLSS) and mixed liquor volatile-suspended solids (MLVSS) concentration during experiment increases from low concentration to about 7.9 and 6.5 g/L, respectively. The average of PO4
3+
-P, total kjeldahl nitrogen (TKN), ammonia and fecal coliform (FC) removal efficiency during the operation period was 62, 98, 70% and 8 log, respectively.
Conclusion:
It is concluded that FS-MBR can be used in the large scale municipal wastewater treatment plants to improve effluent quality due to high removal of COD, BOD
5
, TSS and VSS to meet effluent discharge standards.
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© International Journal of Environmental Health Engineering | Published by Published by
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Online since 21 March, 2012